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I’ve done a bit of digging and I wasn’t able to find any option to use CloudFront for particular types of files on WordPress without the use of a plugin. Since WordPress by default expects it’s assets to be on the same host and in particular folders a plugin is required to override this and serve them from a CDN. Another option might be a service like CloudFlare that would work without any custom WordPress settings and automatically cache content, thus improving performance and reducing bandwidth use.
https://wordpress.org/plugins/aws-cdn-by-wpadmin/ supports multisite setup