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I do not know if Dreamweaver supports this but the problem you are running into is that when you connect via SFTP you start out in the /root directory while your web files would be in /var/www/html
You need to change up a directory to reach / and then navigate to /var/www/html. In Dreamweaver you may need to set the default directory for the connection. If that does not work, using a dedicated FTP/SFTP client like FileZilla should allow you to access your files.